I think that Kingston may be wrong about it being capable of 4gb, but who knows.
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I use a 64-bit OS will all 4GB be recognized?
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Yes.
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And is the 4GB RAM limit due to the MoBo or OS?
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OS, yes
Mobo, yes and no, first the memory has to meet the mobo requirements, and since I cannot find specs from toshiba, we are not sure if the mobo can use 2gb or 4g.
So if your laptop can use 4gb and you put a 32bit OS on it, it will only recognize 3-3.5 in windows.
If your Laptop can only handle 2gb and you put more in there, it will either not post or boot, or it will see the memory incorrectly and cause problems addressing it in windows.
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but can I still use DDR2-800 as an upgrade?
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Waste of money if it is more expensive.
Most likely the biso will not recognize it and get a no post, or it will clock the speed back to 667. It is best to install the memory speed it was designed for, 667.