Netscape and Angelfire are definitely the best EMAIL accounts. They have 0 junk mail. And I do mean 0. 0,0,0! I don't mean 1 or 2 junk mails a month, I mean none at all, period. I didn't log in to Netscape for like half a year, and I didn't get any messages. Now, of course, if you start giving out your email address to companies or people you don't know well, well of couse then you might start getting junk mail. I mean that initially, when you create the account, you won't get any junk. So if you do, hand your email address out carefully. Angelfire is not giving out any addresses right now, though.
Hotmail receives tons of junk mail, Yahoo does not receive many.